Key Takeaways
- Carbon monoxide (CO) is a colorless, odorless, and tasteless gas with a molecular weight of 28.01 g/mol, slightly less dense than air at 0.967 g/L.
- CO has a boiling point of -191.5°C and a melting point of -205.02°C under standard atmospheric pressure.
- The bond dissociation energy of the carbon-oxygen triple bond in CO is 1072 kJ/mol, making it one of the strongest known chemical bonds.
- Global industrial production of CO reaches about 50 million tons annually, primarily via steam reforming of natural gas.
- In the steel industry, CO is produced via the blast furnace process at rates up to 1,200 Nm³/ton of pig iron.
- Syngas, containing 40-60% CO, is produced at over 200 billion cubic meters annually worldwide for chemical synthesis.
- Incomplete combustion of gasoline vehicles emits 1-2% CO by volume in exhaust under stoichiometric conditions.
- Residential wood burning fireplaces emit average 5-10 g CO per kg of wood burned.
- Cigarette smoke contains 4-5% CO by volume, leading to 3-15% COHb in smokers.
- CO exposure at 100 ppm for 4 hours causes headache and fatigue in 50% of people.
- Carboxyhemoglobin (COHb) levels above 10% impair cognitive function and exercise performance.
- Annual CO poisoning deaths in US: 400-500, with 50,000 ER visits.
- CO detectors must alarm at 70 ppm for 1-4 hours per UL 2034 standard.
- EPA NAAQS for 8-hour CO average is 9 ppm, 1-hour 35 ppm since 1971.
- OSHA PEL for CO is 50 ppm 8-hour TWA, 200 ppm ceiling.
Carbon monoxide is a toxic gas produced by combustion and used in industry globally.
Environmental Sources and Levels
- Incomplete combustion of gasoline vehicles emits 1-2% CO by volume in exhaust under stoichiometric conditions.
- Residential wood burning fireplaces emit average 5-10 g CO per kg of wood burned.
- Cigarette smoke contains 4-5% CO by volume, leading to 3-15% COHb in smokers.
- Atmospheric background CO level is 0.1-0.2 ppm globally, rising to 0.5 ppm in urban areas.
- Volcanic emissions contribute 10-20 million tons CO annually worldwide.
- Forest fires emit 20-50 Tg CO per year globally, peaking during El Niño events.
- Power plants burning coal emit 0.1-0.5 kg CO per MWh generated.
- Natural gas appliances like unvented heaters produce 10-50 ppm CO under normal operation.
- Traffic contributes 50-70% of urban CO concentrations, with peaks at 5-10 ppm during rush hour.
- Methane oxidation in troposphere produces 500-1000 Tg CO annually.
- Indoor CO levels from kerosene heaters can reach 100-200 ppm without ventilation.
- Boat engines in enclosed cabins emit up to 4000 ppm CO from exhaust.
- Barbecues used indoors produce 500-1000 ppm CO within minutes.
- Generators placed near homes elevate outdoor CO to 100-500 ppm at 5 meters.
- Snow-blocked tailpipes in vehicles can build CO to 1-5% in cabin air.
- Industrial flaring emits 1-2 g CO per m³ of flared gas.
- Aircraft exhaust contributes 0.01-0.05 ppm CO at cruising altitudes.
- Urban ambient CO averages 1-3 ppm in major cities like Los Angeles pre-CARB regulations.
- CO half-life in atmosphere is 1-2 months, primarily oxidized by OH radicals.
Environmental Sources and Levels Interpretation
Health Impacts and Poisoning
- CO exposure at 100 ppm for 4 hours causes headache and fatigue in 50% of people.
- Carboxyhemoglobin (COHb) levels above 10% impair cognitive function and exercise performance.
- Annual CO poisoning deaths in US: 400-500, with 50,000 ER visits.
- Symptoms at 400 ppm include nausea and dizziness after 2-3 hours exposure.
- Fetuses are 10-20% more sensitive to CO, with miscarriage risk doubling at 5% COHb.
- Chronic low-level CO (1-5 ppm) links to increased cardiovascular hospitalizations by 13%.
- LD50 for CO inhalation in rats is 1807 ppm for 4 hours.
- 50% COHb causes unconsciousness; 70% is rapidly fatal without intervention.
- CO poisoning accounts for 1-2% of all poisoning deaths globally, ~10,000/year.
- Elderly (>65) have 2-3x higher mortality rate from CO poisoning.
- Hyperbaric oxygen therapy reduces half-time of COHb elimination from 4-6h to 20-30 min.
- CO exacerbates angina in heart patients at 50 ppm over 1 hour.
- Children under 5 show neurological deficits post-CO exposure at >20% COHb.
- CO binds myoglobin 40x stronger than O2, impairing muscle oxygen delivery at 10% COHb.
- Post-CO poisoning, 10-30% develop delayed neuropsychiatric syndrome weeks later.
- Smokers average 5-10% COHb, increasing atherosclerosis risk by 2-4x.
- CO poisoning misdiagnosed as flu in 30-50% of cases initially.
- Occupational CO exposure limit is 50 ppm TWA per OSHA.
- CO at 800 ppm causes convulsions and coma in 2 hours.
- Winter months see 5x more CO poisonings due to heating.
Health Impacts and Poisoning Interpretation
Production and Industrial Uses
- Global industrial production of CO reaches about 50 million tons annually, primarily via steam reforming of natural gas.
- In the steel industry, CO is produced via the blast furnace process at rates up to 1,200 Nm³/ton of pig iron.
- Syngas, containing 40-60% CO, is produced at over 200 billion cubic meters annually worldwide for chemical synthesis.
- CO is used in the Mond process for nickel purification, reacting to form volatile Ni(CO)₄ at yields >95%.
- Hydroformylation (oxo process) consumes about 10 million tons of CO annually to produce aldehydes from alkenes.
- In methanol synthesis, CO + 2H₂ → CH₃OH uses 20-30 million tons of CO equivalent per year globally.
- Fischer-Tropsch process converts CO-rich syngas to hydrocarbons, producing 1-2 million barrels/day in major plants.
- CO is generated in partial oxidation of hydrocarbons, with methane partial oxidation yielding 70-80% CO selectivity.
- Coal gasification produces syngas with 30-50% CO content, accounting for 20% of global syngas production.
- Acetic acid production via Monsanto process uses CO and methanol, consuming 5 million tons CO/year.
- CO laser uses CO as the active medium, achieving wavelengths from 2.5 to 20 μm with power outputs up to 100 kW.
- In metal carbonyls production, like Fe(CO)₅, CO usage is about 100,000 tons annually for catalysts.
- Steam reforming of natural gas produces 50-60% H₂ and 30-40% CO, with global capacity >100 million tons H₂ equivalent.
- Biomass gasification yields syngas with 15-30% CO, contributing to 5% of renewable syngas production.
- Dry reforming of methane (CO₂ + CH₄ → 2CO + 2H₂) is emerging, with pilot plants producing 10-20 tons CO/day.
Production and Industrial Uses Interpretation
Properties and Chemistry
- Carbon monoxide (CO) is a colorless, odorless, and tasteless gas with a molecular weight of 28.01 g/mol, slightly less dense than air at 0.967 g/L.
- CO has a boiling point of -191.5°C and a melting point of -205.02°C under standard atmospheric pressure.
- The bond dissociation energy of the carbon-oxygen triple bond in CO is 1072 kJ/mol, making it one of the strongest known chemical bonds.
- CO exhibits a dipole moment of 0.122 Debye due to its slight polarity from the lone pair on carbon.
- Infrared absorption spectrum of CO shows a strong peak at 2143 cm⁻¹ corresponding to the C≡O stretch vibration.
- CO solubility in water at 20°C and 1 atm is 0.0284 g/L, increasing with pressure per Henry's law constant of 0.934 L·atm/mol.
- The ionization energy of CO is 14.014 eV, with the first ionization removing an electron from the 5σ orbital.
- CO forms coordination complexes with metals, such as [Fe(CO)₅], where it acts as a ligand via σ-donation and π-backbonding.
- Thermal conductivity of CO at 25°C and 1 atm is 0.02476 W/m·K.
- Viscosity of gaseous CO at 20°C is 1.77 × 10⁻⁵ Pa·s.
- CO has a critical temperature of -140.2°C and critical pressure of 34.99 atm.
- Heat capacity (Cp) of CO gas at 25°C is 29.14 J/mol·K.
- CO reacts with oxygen to form CO₂ with an activation energy of approximately 167 kJ/mol in the gas phase.
- Equilibrium constant for CO + H₂O ⇌ CO₂ + H₂ (water-gas shift) at 227°C is K=10.
- CO binds to hemoglobin with an affinity 210-250 times greater than oxygen, forming carboxyhemoglobin (COHb).
Properties and Chemistry Interpretation
Safety Measures and Regulations
- CO detectors must alarm at 70 ppm for 1-4 hours per UL 2034 standard.
- EPA NAAQS for 8-hour CO average is 9 ppm, 1-hour 35 ppm since 1971.
- OSHA PEL for CO is 50 ppm 8-hour TWA, 200 ppm ceiling.
- NIOSH REL is 35 ppm TWA, 200 ppm ceiling for 15 min.
- WHO indoor guideline: 9 ppm 8-hr, 25 ppm 1-hr, 90 ppm 15-min.
- All new homes in UK require CO alarms since 2001 Building Regs.
- US CPSC mandates CO alarms in all dwellings since 2011.
- NFPA 720 requires CO detectors in residences with fuel-burning appliances.
- California AB 1837 bans single-family home sales without CO detectors.
- EU Directive 2000/39/EC sets workplace CO limit at 30 mg/m³ (26 ppm).
- Portable generator CO emissions regulated <430 ppm at 23 ft per EPA.
- Vent-free gas heaters limited to 0.01% CO emission by ANSI Z21.11.2.
- Annual CO detector testing required in hotels per NFPA 101.
- Canada mandates CO alarms in all new dwellings since 2006.
- Australia AS 3780 standard for CO alarms: alarm at 70 ppm within 120 min.
- US annual CO deaths dropped 50% from 1999-2010 due to detectors.
- Chimney sweeps required annually for wood stoves per EPA.
- Forklift CO emissions limited to 200 ppm average per OSHA.
- CO exposure monitoring required in tunnels per EU Dir 92/104.
- Massachusetts law requires CO detectors in all residential buildings.
Safety Measures and Regulations Interpretation
Sources & References
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