Key Takeaways
- The density of Low-Density Polyethylene (LDPE) typically ranges from 0.910 to 0.925 g/cm³ at 23°C
- High-Density Polyethylene (HDPE) has a density between 0.941 and 0.965 g/cm³, making it suitable for rigid applications
- Linear Low-Density Polyethylene (LLDPE) exhibits a density of 0.915 to 0.925 g/cm³ with improved tensile properties over LDPE
- The tensile strength of HDPE at 23°C is 22-29 MPa according to ISO 527 for blow molding grades
- LDPE elongation at break exceeds 600% in uniaxial tension tests at room temperature
- Young's modulus for LLDPE is 200-400 MPa depending on density and comonomer type
- Melting temperature of LDPE is 105-115°C with peak at 112°C by DSC at 10°C/min
- HDPE crystallizes at 110-120°C cooling rate dependent, with heat of fusion 150-200 J/g
- Glass transition temperature Tg of PE is -120 to -80°C for amorphous regions by DSC
- Volume resistivity of LDPE is >10^16 ohm·cm at 23°C and 50% RH
- Dielectric strength of HDPE film is 60-80 kV/mm in air per ASTM D149
- Dissipation factor of PE at 1 kHz is <0.0005 for communication cables
- Global production capacity of polyethylene reached 109 million metric tons per year in 2022
- HDPE accounts for 53% of total PE production worldwide as of 2023
- Annual ethylene consumption for PE is over 100 million tonnes, representing 60% of total ethylene use
Polyethylene's varying density and strength enable countless essential products worldwide.
Applications, Market, and Environmental Impact
- HDPE used in 12% of global plastic packaging market valued at $40 billion in 2023
- Bottles and containers account for 35% of HDPE consumption worldwide
- PE pipes represent 20% of PE demand with 4.5 million tons/year growth projected to 2028
- Agricultural films use 7 million tons of LLDPE annually for mulching and greenhouses
- Global PE market size was $142 billion in 2022 with 4.5% CAGR forecast to 2030
- UHMWPE in medical implants like hip joints totals 10,000 tons/year market value $2B
- PE in flexible packaging grew to 25 million tons in 2023 driven by e-commerce
- Rotomolded PE products for toys and tanks use 3 million tons annually
- LDPE grocery bags banned in 100+ countries covering 40% of global PE film use
- Automotive fuel tanks from HDPE number 50 million units/year reducing weight by 20%
- PE wax market for lubricants and coatings is 1.2 million tons valued at $1.5B in 2023
- Ocean plastic pollution from PE mismanaged waste is 1.5 million tons/year
- Recycled PE content in new bottles reached 25% average in EU by 2023 regulation
- Geomembrane liners from HDPE cover 500,000 acres for landfills annually
- PE in 3D printing filaments market grows at 20% CAGR to $500M by 2027
- Carbon footprint of virgin HDPE production is 1.8-2.2 kg CO2 eq/kg
- Microplastics from PE tire wear contribute 28% of ocean microplastics or 1 million tons/year
- Price of HDPE spot market averaged $1200/ton in US Q4 2023
- Bio-PE adoption in cosmetics packaging up 15% to 50,000 tons/year for sustainability
- PE recycling plants worldwide process 9 million tons/year with 30% recovery efficiency
Applications, Market, and Environmental Impact Interpretation
Chemical Properties
- Volume resistivity of LDPE is >10^16 ohm·cm at 23°C and 50% RH
- Dielectric strength of HDPE film is 60-80 kV/mm in air per ASTM D149
- Dissipation factor of PE at 1 kHz is <0.0005 for communication cables
- Carbon black content in UV-stabilized HDPE is 2-3% by weight for pipes
- Monomer residue in HDPE polymerization is <1 ppm ethylene per FDA 21 CFR 177.1520
- Antioxidant concentration in PE compounds is 0.1-0.5 wt% Irganox 1010 equivalent
- pH stability of PE ranges from 2-12 with no degradation after 1000 hours immersion
- Swell index in hydrocarbons for LDPE is <10% volume change in toluene at 23°C
- Chlorine resistance of PEX pipes shows <10% strength loss after 4000 hours at 40 ppm
- Biodegradation rate of PE in soil is <0.1% weight loss per year without pro-oxidants
- Ash content of virgin PE is <0.1% by thermogravimetric analysis at 800°C
- Melt flow rate sensitivity to shear for metallocene PE is lower with PDI <2.5
- Extractables in hot water for food-grade PE <0.5 mg/dm² per EU 10/2011
Chemical Properties Interpretation
Mechanical Properties
- The tensile strength of HDPE at 23°C is 22-29 MPa according to ISO 527 for blow molding grades
- LDPE elongation at break exceeds 600% in uniaxial tension tests at room temperature
- Young's modulus for LLDPE is 200-400 MPa depending on density and comonomer type
- Notched Izod impact strength of HDPE at 23°C is 20-40 J/m for pipe grades
- Flexural strength of MDPE is 15-25 MPa at yield per ASTM D790
- Fatigue strength of UHMWPE under cyclic loading is >10^7 cycles at 5 MPa stress amplitude
- Shear modulus of LDPE at 1 Hz and 23°C is approximately 100-200 MPa
- Compressive yield strength of HDPE foam is 0.5-2.0 MPa at 10% deformation for 30 kg/m³ density
- Burst pressure resistance of HDPE pipes is up to 4 times the working pressure per ISO 4427
- Tensile creep rupture time for PEX-a at 80°C and 3.4 MPa exceeds 50 years
- Dynamic mechanical analysis shows HDPE storage modulus peaks at 1-2 GPa above glass transition
- Fracture toughness K_IC of UHMWPE is 3-5 MPa·m^{1/2} for orthopedic grades
- Wear rate of HDPE in Taber abrasion test is <0.1 mg/1000 cycles under 1000g load
- Bending modulus of LLDPE films is 150-250 MPa at 23°C per ASTM D882
- Impact resistance of cross-linked PE at -20°C is >10 ft-lb/in for rotational molding
- Ultimate tensile strength of recycled HDPE is 18-25 MPa after reprocessing
- Modulus of elasticity in torsion for PE is 0.3-0.5 GPa at room temperature
- Environmental stress crack resistance (ESCR) of HDPE in 10% Igepal exceeds 500 hours per ASTM D1693
Mechanical Properties Interpretation
Physical Properties
- The density of Low-Density Polyethylene (LDPE) typically ranges from 0.910 to 0.925 g/cm³ at 23°C
- High-Density Polyethylene (HDPE) has a density between 0.941 and 0.965 g/cm³, making it suitable for rigid applications
- Linear Low-Density Polyethylene (LLDPE) exhibits a density of 0.915 to 0.925 g/cm³ with improved tensile properties over LDPE
- The melt index of LDPE varies from 0.1 to 50 g/10 min under ASTM D1238 conditions at 190°C/2.16 kg
- HDPE's crystallinity is approximately 60-80%, contributing to its higher strength compared to LDPE's 40-55%
- Ultra-High Molecular Weight Polyethylene (UHMWPE) has a molecular weight exceeding 3.5 million g/mol, resulting in exceptional wear resistance
- Cross-linked Polyethylene (PEX) shows a gel content of over 65% after irradiation crosslinking process
- The refractive index of PE is around 1.51-1.52 for sodium D-line at 20°C
- LDPE has a specific heat capacity of 2.3 J/g·K at 20°C, increasing to 2.6 J/g·K near melting point
- HDPE's water absorption is less than 0.01% after 24 hours immersion at 23°C per ASTM D570
- The coefficient of linear thermal expansion for HDPE is 1.2-1.8 x 10^-4 /°C between 20-60°C
- LDPE film thickness for grocery bags averages 0.025 mm (1 mil), with tensile strength of 10-20 MPa
- UHMWPE's porosity in sintered form is controlled below 1% for medical implants
- The surface tension of molten PE at 200°C is approximately 30-35 mN/m
- HDPE pipes have an inside diameter tolerance of ±1% for sizes up to 24 inches per AWWA C906
- LDPE's hardness on Shore D scale is 45-55, indicating flexibility for squeeze bottles
- The dielectric constant of PE at 1 MHz is 2.25-2.35 for LDPE
- Molecular weight distribution (MWD) polydispersity index for Ziegler-Natta HDPE is 4-8
- PE foam density ranges from 15-100 kg/m³ depending on expansion ratio for packaging
- The gloss level of extruded HDPE film is 40-60% at 45° angle per ASTM D2457
- Tensile modulus of elasticity for LDPE is 150-300 MPa at 23°C
- HDPE's yield strength is 20-30 MPa for injection molded grades per ISO 527
- Elongation at break for LLDPE films reaches 500-800% in machine direction
- Impact strength of HDPE at -40°C is >5 kJ/m² notched Izod per ASTM D256
- Flexural modulus for medium-density PE (MDPE) is 400-800 MPa at 23°C
- Tear strength of LDPE blown film is 200-400 g/μm in dart drop test ASTM D1709
- Compressive strength of UHMWPE is 20-30 MPa at 10% strain
- Poisson's ratio for HDPE is approximately 0.42-0.46 under tensile loading
- Creep modulus of LDPE after 1000 hours at 23°C and 4 MPa is 100-200 MPa
- Hardness of crosslinked PE (PEX) is Shore D 55-65 post-crosslinking
Physical Properties Interpretation
Production and Manufacturing
- Global production capacity of polyethylene reached 109 million metric tons per year in 2022
- HDPE accounts for 53% of total PE production worldwide as of 2023
- Annual ethylene consumption for PE is over 100 million tonnes, representing 60% of total ethylene use
- Ziegler-Natta catalysis produces 70% of HDPE via slurry or gas phase processes
- Metallocene catalysts yield LLDPE with narrow MWD, comprising 15% of PE market since 2000
- China holds 35% of global PE production capacity at 38 million tons/year in 2023
- Energy intensity for HDPE production is 70-80 GJ/tonne including cracking
- Slurry loop reactor for HDPE operates at 80-110°C and 20-60 bar pressure
- Bimodal PE production via cascade reactors achieves 20-30% higher throughput
- Autoclave process for LDPE uses 150-300 MPa pressure and 150-300°C temperature
- Catalyst consumption in PE plants is 1-5 ppm Ti for Phillips loop process
- Recycling rate of post-consumer PE in Europe reached 28% in 2022
- Gas phase Unipol process produces 40% of world's LLDPE at >50,000 tons/year per reactor
- Ethylene conversion yield in HDPE slurry process exceeds 99% with flash devolatilization
- Number of PE plants worldwide is over 300 with average capacity 400,000 tons/year
- Tubular reactor LDPE plants have residence time of 30-120 seconds for high-pressure polymerization
- Bio-based PE production from sugarcane reached 200,000 tons/year by Braskem in 2023
- HDPE resin yield per kg catalyst is 100,000-500,000 in modern metallocene systems
- Global LDPE production was 18.5 million tons in 2022, down 2% from prior year
- PE film extrusion lines produce 500-2000 kg/hour with die gap 0.5-2 mm
Production and Manufacturing Interpretation
Thermal Properties
- Melting temperature of LDPE is 105-115°C with peak at 112°C by DSC at 10°C/min
- HDPE crystallizes at 110-120°C cooling rate dependent, with heat of fusion 150-200 J/g
- Glass transition temperature Tg of PE is -120 to -80°C for amorphous regions by DSC
- Thermal conductivity of HDPE is 0.42-0.51 W/m·K at 23°C
- Vicat softening point for LDPE is 85-95°C under 10N load per ISO 306
- Heat deflection temperature (HDT) of HDPE at 0.45 MPa is 50-60°C per ASTM D648
- Oxidative induction time (OIT) for stabilized HDPE exceeds 20 minutes at 200°C by DSC
- Coefficient of thermal expansion for LDPE is 1.8-2.5 x 10^{-4} /°C from 0-100°C
- Specific heat of molten PE at 200°C is 2.5-2.8 J/g·K
- Flammability rating of PE is HB per UL 94 with oxygen index 17-19%
- Thermal diffusivity of HDPE is 1.5-2.0 x 10^{-7} m²/s at room temperature
- Deflection temperature under load for PEX-b is 90-95°C at 0.5 MPa
- Heat capacity ratio Cp/Cv for PE gas phase is approximately 1.1 at 298K
- Ignition temperature of PE in air is 340-360°C under ASTM E659
- Shrinkage of injection molded HDPE is 1.5-3.0% in flow direction
Thermal Properties Interpretation
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